Crystal structure of heterometallic complexes
A team of scientists from the Institute of General and Inorganic Chemistry. NS. Kurnakov RAS, together with their foreign colleagues, synthesized and investigated a series of new heterometallic coordination compounds containing lanthanide and two different transition metal ions. The resulting compounds can be used to create elements for ultra-dense information storage. The results are published in the leading international journal of inorganic chemistry, Dalton Transactions.
Heterometallic complexes are nano-sized molecular objects that contain ions of at least two metals. Their unusual properties are due to the presence of metal atoms of various natures in the molecule, due to which fundamentally new characteristics appear.
“For more than ten years, our laboratory has been developing on the production and use of heterometallic complexes in which lanthanide ions (a family of 15 rare-earth chemical elements) form the skeleton of the molecule, and transition metal atoms are part of the fragments connecting them,” says a senior researcher at the Laboratory of magnetic materials IGIC RAS, candidate of chemical sciences Pavel Koroteev. “In new experiments, we managed to synthesize unique complexes containing three different metals. The resulting substances combine in their structure the atoms of two transition metals – iron and chromium, and the atoms of rare earth elements – lanthanides or yttrium. Quite a few similar trimetallic complexes are known, and the number of trimetallic complexes containing an organometallic fragment is only a few. “
The study of the magnetic properties of the obtained complexes, carried out at the Center for Research. Paul Pascal from the University of Bordeaux (France), together with the group of the outstanding magnetochemist Rodolphe Klerac, made it possible to establish that the complexes containing terbium, dysprosium, and holmium are molecular magnets. Such compounds are of interest as a means of ultradense storage of information, since they can potentially store one bit of information in each molecule, which increases the density of its recording on storage devices, therefore, can lead to their significant miniaturization.
This work was supported by a grant from the Ministry of Science and Higher Education of the Russian Federation (project 075-15-2020-779).
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